Abstract View

Author(s): Dipti Sahu, D.P. Bisen, Nameeta Brahme, Kanchan Tiwari, Aastha Sahu

Email(s): dipti8332@gmail.com

Address: School of Studies in Physics and Astrophysics, Pt. Ravishankar Shukla University, Raipur (C.G.) 492010, India.
School of Studies in Physics and Astrophysics, Pt. Ravishankar Shukla University, Raipur (C.G.) 492010, India.
School of Studies in Physics and Astrophysics, Pt. Ravishankar Shukla University, Raipur (C.G.) 492010, India.
Govt. Nagarjuna P.G. College of Science, Raipur (C.G.).
Guru Ghasidas Vishwavidyalaya, Bilaspur (C.G.), India.

Corresponding Author: dipti8332@gmail.com

Published In:   Volume - 36,      Issue - 1,     Year - 2023

DOI: 10.52228/JRUB.2023-36-1-10  

In this paper, Eu3+ doped phosphor Li4SrCa(SiO4)2 is successfully synthesized via a solid-state reaction method at high temperatures. Structure characterization is determined using X-ray diffraction (XRD). Surface morphology was analyzed using Field emission scanning electron microscopy(FESEM). The EDX spectra confirm the elements present in Li4SrCa(SiO4)2:Eu3+ phosphor. Photoluminescence(PL) spectra of Li4SrCa(SiO4)2:Eu3+ phosphor was efficiently excited by UV range 220-450nm and under the excitation 395nm phosphors shows good intensity with an orange-red intense peak at 591nm and 619 nm was due to 4D0-7F1 and 4D0-7F2 transition respectively. Commission International del’ Eclairage (CIE) color coordinate was calculated, which confirms the Eu3+ doped phosphor with a CIE value of (x=0.6259, y=0.3737). This phosphor is considered to be a new promising orange-red emitting phosphor for WLEDs application. This phosphor may be used for solid-state lighting.

Cite this article:
Sahu, Bisen, Brahme, Tiwari and Sahu (2023). Structural, Compositional and Photoluminescence Studies of Li4SrCa(SiO4)2: Eu3+ Red Phosphor Synthesized by Solid State Reaction Method. Journal of Ravishankar University (Part-B: Science), 36(1), pp. 104-112.DOI: https://doi.org/10.52228/JRUB.2023-36-1-10


[1]      R. Paikaray, T. Badapanda, H. Mohapatra, T. Richhariya, S.N. Tripathy, Investigation of structural, photoluminescence , and thermoluminescence properties of Praseodymium doped CaWO 4 phosphor, Mater. Today Commun. 31 (2022) 103802. https://doi.org/10.1016/j.mtcomm.2022.103802.

[2]      N.F. Cano, A.J. Gonsalez-Vasquez, T.K.G. Rao, K. V Turpo-huahuasoncco, E.A. Canaza-mamani, A.H. Lopez-gonzales, H.S. Javier-ccallata, J.S. Ayala-arenas, R. Rocca, N.B. Silva-carrera, F.D. Chubaci, S. Watanabe, Journal of Physics and Chemistry of Solids Structural characterization , continuous-wave optically stimulated luminescence , and correlation between thermoluminescence and EPR of Ce-doped Ca 2 Al 2 SiO 7 phosphor synthesized by a solid-state reaction method, 170 (2022). https://doi.org/10.1016/j.jpcs.2022.110928.

[3]      I.P. Sahu, D.P. Bisen, N. Brahme, Europium doped di-calcium magnesium di-silicate orange–red emitting phosphor by solid state reaction m ethod, J. Radiat. Res. Appl. Sci. 8 (2015) 381–388. https://doi.org/10.1016/j.jrras.2015.02.007.

[4]      B. Vasanthi, N. Gopakumar, P.S. Anjana, Structural , optical and luminescence properties of BaLaGa 3 O 7 : x Eu 3 + ceramic phosphors, J. Lumin. 241 (2022) 118486. https://doi.org/10.1016/j.jlumin.2021.118486.

[5]      P.M. Kakade, A.R. Kachere, P.D. Sahare, A. V Deshmukh, S.D. Dhole, S.R. Jadkar, N.T. Mandlik, Structural, compositional and luminescence studies of Y2O3_Eu3+ nanophosphor synthesized by sol-gel method, J. Alloys Compd. 928 (2022) 167106. https://doi.org/10.1016/j.jallcom.2022.167106.

[6]      S. Ye, F. Xiao, Y.X. Pan, Y.Y. Ma, Q.Y. Zhang, Phosphors in phosphor-converted white light-emitting diodes : Recent advances in materials , techniques and properties, 71 (2010) 1–34. https://doi.org/10.1016/j.mser.2010.07.001.

[7]      G.C. Righini, U. Caldiño, C. Falcony, M. Ferrari, S. Pelli, Rare-Earth Phosphors for the Control of WLED ’ s Colour Output : State of the Art, (2014) 5–8.

[8]      R.S.C. Advances, L. Shi, H. Zhang, Q. Su, RSC Advances Eu 3 + doped Sr 2 CeO 4 phosphors for thermometry : single-color or two-color, 3 (2011) 298–304. https://doi.org/10.1039/c1ra00221j.

[9]      Determination of optical and structural properties of lithium silicate ceramics with different ratios of Sm doped, 33 (2022). https://doi.org/10.1016/j.apt.2022.103685.

[10]    Z. Xu, Y. Zhu, Q. Luo, Y. Pan, W. Wang, X. Liu, L. Li, Anomalous preparation , intense 5 D 0 → 7 F 4 emission and adjustable double center emission of Eu 3 + and Eu 2 + codoped Ca 2 Al 2 SiO 7, Ceram. Int. (2019) 0–1. https://doi.org/10.1016/j.ceramint.2019.07.017.

[11]    S.G.M. Mushtaque, A.R. Kadam, S.J. Dhoble, High color purity and color tunability in Sm3+/ Eu3+ activated/ co-activated Sr6Ca4(PO4)6F2 phosphor for WLED and display devices application, J. Mol. Struct. 1274 (2023) 134510. https://doi.org/10.1016/j.molstruc.2022.134510.

[12]    C.M. Mehare, M. Jog, M.D. Mehare, N.S. Dhoble, S.J. Dhoble, Synthesis and photoluminescence properties of novel red-emitting KMg4(PO4)3: Eu3+phosphors for UV-excited white-light emitting diodes, J. Phys. Conf. Ser. 1913 (2021). https://doi.org/10.1088/1742-6596/1913/1/012032.

[13]    C.M. Nandanwar, A.N. Yerpude, N.S. Kokode, S.J. Dhoble, Wet chemical synthesis of BiPO4:Eu3+ phosphor for w-LED application, Luminescence. (2022) 1800–1804. https://doi.org/10.1002/bio.4340.

[14]    Y.R. Parauha, S.J. Dhoble, Color-tunable luminescence, energy transfer behavior and I-V characteristics of Dy3+,Eu3+ co-doped La(PO4) phosphors for WLEDs and solar applications, New J. Chem. 46 (2022) 6230–6243. https://doi.org/10.1039/d2nj00232a.

[15]    I. Pekgözlü, E. Erdoʇmuş, M. Yilmaz, Synthesis and photoluminescence properties of Li4SrCa(SiO4)2: M (M: Pb2+and Bi3+), J. Lumin. 161 (2015) 160–163. https://doi.org/10.1016/j.jlumin.2015.01.009.

[16]    J. Zhang, W. Zhang, Y. He, W. Zhou, L. Yu, S. Lian, Z. Li, M. Gong, Site-occupancy on the luminescence properties of a single-phase Li 4SrCa(SiO4)2:Eu2+ phosphor, Ceram. Int. 40 (2014) 9831–9834. https://doi.org/10.1016/j.ceramint.2014.02.073.

[17]    Z. Wang, Y. Li, X. Liu, X. Wei, Y. Chen, F. Zhou, Y. Wang, Photoluminescence performance of thulium doped Li4SrCa(SiO 4)2 under irradiation of ultraviolet and vacuum ultraviolet lights, Mater. Res. Bull. 59 (2014) 295–299. https://doi.org/10.1016/j.materresbull.2014.07.043.

[18]    A. Akella, D.A. Keszler, The New Orthosilicate Li4SrCa(SiO4)2: Structure and Eu2+ Luminescence, Inorg. Chem. 34 (1995) 1308–1310. https://doi.org/10.1021/ic00110a005.

[19]    R. Shi, L. Ning, Y. Huang, Y. Tao, L. Zheng, Z. Li, H. Liang, Li 4 SrCa(SiO 4 ) 2 :Eu 2+ : A Potential Temperature Sensor with Unique Optical Thermometric Properties, ACS Appl. Mater. Interfaces. 11 (2019) 9691–9695. https://doi.org/10.1021/acsami.8b22754.

[20]    R. Shi, X. Huang, T. Liu, L. Lin, C. Liu, Y. Huang, L. Zheng, L. Ning, H. Liang, Optical Properties of Ce-Doped Li4SrCa(SiO4)2: A Combined Experimental and Theoretical Study, Inorg. Chem. 57 (2018) 1116–1124. https://doi.org/10.1021/acs.inorgchem.7b02561.

[21]    X.M. Zhang, W.L. Li, H.J. Seo, Luminescence and energy transfer in Eu2+, Mn2+ co-doped Li4SrCa(SiO4)2 for white light-emitting-diodes, Phys. Lett. Sect. A Gen. At. Solid State Phys. 373 (2009) 3486–3489. https://doi.org/10.1016/j.physleta.2009.07.052.

[22]    J. Zhang, W. Zhang, Z. Qiu, W. Zhou, L. Yu, Z. Li, S. Lian, Li4SrCa(SiO4)2:Ce3+, a highly efficient near-UV and blue emitting orthosilicate phosphor, J. Alloys Compd. 646 (2015) 315–320. https://doi.org/10.1016/j.jallcom.2015.05.280.

[23]    X. Zhang, H.J. Seo, Color tunable and thermally stable luminescence of Tb 3+ doped Li 4SrCa(SiO 4) 2 phosphors, Mater. Res. Bull. 47 (2012) 2012–2015. https://doi.org/10.1016/j.materresbull.2012.04.010.

[24]    S. Chand, R. Mehra, V. Chopra, Recent advancements in calcium based phosphate materials for luminescence applications, J. Lumin. 252 (2022) 119383. https://doi.org/10.1016/j.jlumin.2022.119383.

[25]    X.M. Zhang, W.L. Li, L. Shi, X.B. Qiao, H.J. Seo, Photoluminescence properties of blue-emitting Li4SrCa(SiO 4)2:Eu2+ phosphor for solid-state lighting, Appl. Phys. B Lasers Opt. 99 (2010) 279–284. https://doi.org/10.1007/s00340-009-3820-5.

[26]    T. Richhariya, N. Brahme, D.P. Bisen, T. Badapanda, A. Choubey, Y. Patle, E. Chandrawanshi, Synthesis and optical characterization of Dy3+ doped barium alumino silicate phosphor, Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 273 (2021) 115445. https://doi.org/10.1016/j.mseb.2021.115445.

[27]    E. Chandrawanshi, D.P. Bisen, N. Brahme, G. Banjare, T. Richhariya, Y. Patle, Photoluminescence and comparative thermoluminescence studies of UV/γ-irradiated Dy3+ doped bismuth silicate phosphor, J. Mater. Sci. Mater. Electron. 31 (2020) 14454–14465. https://doi.org/10.1007/s10854-020-04005-2.

[28]    Y. Patle, N. Brahme, D.P. Bisen, T. Richhariya, E. Chandrawanshi, A. Choubey, M. Tiwari, Study of Photoluminescence,Thermoluminescence, and Afterglow properties of Dy3+ doped Ba2ZnSi2O7 phosphor, Optik (Stuttg). 226 (2021) 165896. https://doi.org/10.1016/j.ijleo.2020.165896.

Related Images:

Recent Images

Chlorpyrifos Mediated Amendment in Protein Profiling of Bacillus spp.
Structural, Compositional and Photoluminescence Studies of Li4SrCa(SiO4)2: Eu3+ Red Phosphor Synthesized by Solid State Reaction Method
Formulation and Characterization of Magnetically Responsive Mesalamine Microspheres for Colon Targeting
Development of Non-Invasive Technique for Heart Rate Detection Using Facial Videos
Human Part Semantic Segmentation Using CDGNET Architecture for Human Activity Recognition
Lifestyle Modification Therapy and its Effect on Weight Status of Non-Alcoholic Male Liver Disease Patients
Exploring Life Cycle Analysis in Developing Sustainable Communities in Chhattisgarh
Monitoring the Concentration of Lead in the Industrial Wastewater of Baloda Bazar District
Impact of Climate Change on Paddy Yield in Bastar District of Chhattisgarh
Chemical Pollutants: A Concern to The Environment


Recomonded Articles:

Author(s): Swati Jain; Somesh Kumar Dewangan

DOI: 10.52228/JRUB.2021-34-1-9         Access: Open Access Read More

Author(s): Anil Kumar Verma*; Swati Sahu; Mohan Patel; Sanjay Tiwari

DOI: 10.52228/JRUB.2020-33-1-5         Access: Open Access Read More

Author(s): D.K. Sen; S. Bhushan

DOI:         Access: Open Access Read More

Author(s): Yogesh Kumar Dongre; Sanjay Tiwari

DOI: 10.52228/JRUB.2022-35-1-3         Access: Open Access Read More

Author(s): Neelu Singhai; Sati Prasad Banerjee

DOI:         Access: Open Access Read More

Author(s): Yogyata Chawre; Lakshita Dewangan; Ankita Beena Kujur; Indrapal Karbhal; Rekha Nagwanshi; Vishal Jain; Manmohan L. Satnami

DOI: 10.52228/JRUB.2022-35-1-7         Access: Open Access Read More

Author(s): Sachchidanand Shukla; Geeta Singh; Laxmi Kant Singh

DOI:         Access: Open Access Read More

Author(s): R.C. Maurya;A.K. Sharma;P.K. Vishwkarma;J.M. Mir;B.A. Malik;D.K. Rajak

DOI:         Access: Open Access Read More

Author(s): Mohammad A Rashid

DOI:         Access: Open Access Read More

Author(s): Rajendra Jangde; Deependra Singh

DOI:         Access: Open Access Read More

Author(s): Deepika Mahobiya; A K Gupta

DOI:         Access: Open Access Read More

Author(s): Sandhya Chandrakar; AK Gupta

DOI:         Access: Open Access Read More

Author(s): Baikuntha; Kamlesh Dadsena

DOI:         Access: Open Access Read More