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Author(s): Jyoti Goswami, Thakur Vikram Singh, Chhaya Bhatt, Deepak Kumar Sahu, Kalpana Wani, Ajay Kumar Sahu, Prashant Mundeja, Manish Kumar Rai*, Joyec Rai

Email(s): mkjkchem@gmail.com. , jyoti.chemistry11@gmail.com

Address: School of Studies in Chemistry, Pt. Ravishankar Shukla University Raipur (Chhattisgarh), 492010, India
Chhattisgarh Council of Science and Technology, Saddu Rd Mowa, Raipur (Chhattisgarh), 492014, India

Published In:   Volume - 33,      Issue - 1,     Year - 2020

DOI: 10.52228/JRUB.2020-33-1-9  

ABSTRACT:
Pesticides are designated mixture of substances for extenuating and destroying any group of pests such as insects and vegetation. Pymetrozine [6-methyl-4-[(E)-pyridin-3-ylmethylideneamino]-2, 5-dihydro-1, 2, 4-triazin-3-one] is a pyridine azomethine compound which represents a class of insecticide. A Spectrophotometric method has been developed on the modified Fujiwara reaction for the determination of pymetrozine. Pymetrozine directly reacts with chloroform the 45-500C turns out the violet color in the formation of Schiff’s Base (Glutaconic Aldehyde). In the present reaction, the violet color obtained is discharged with a few drops of acetic acid followed by the addition of p- nitro aniline reagent which gives yellow color dyes. The absorption maxima of yellow-colored dye measured at 430 nm. Beer’s law is obeyed over the range of 1 to 10 µg per 10 ml of pymetrozine. The molar absorptivity of the colored system is 1.38×105 L mol-1 and Sandall’s sensitivity is 1.0×10-3µg cm-2. This method is free from the interference of other interfering and can be successfully applied for the determination of various ecological samples.

Cite this article:
Goswami et al. (2020). An Extractive Spectrophotometric Method for the Determination of Pymetrozine in Various Ecological Samples of Bilaspur District (C.G.). Journal of Ravishankar University (Part-B: Science), 33(1), pp. 65-72.DOI: https://doi.org/10.52228/JRUB.2020-33-1-9


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